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Wastewater-based epidemiology (WBE) is a powerful and cost-effective tool for investigating chemicals consumption/pathogens infection and health status of populations, and is rapidly evolving as COVID-19 continues to ravage the world. This paper reviews the significant developments and breakthroughs of WBE in 2021 including collection, pretreatment and analysis of sewage samples, materials stability, correction factors calculation and uncertainty analysis, implementation cases and so on, based on the research findings published in international top academic journals or the most influential achievements. It provides reference for clarifying the development of WBE and promoting the research and application of WBE.
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Water clarity is a key parameter for assessing changes of aquatic environment. Coastal waters are complex and variable, remote sensing of water clarity for it is often limited by low spatial resolution. The Sentinel-2 Multi-Spectral Instrument (MSI) imagery with a resolution of up to 10 m are employed to solve the problem from 2017 to 2021. Distribution and characteristics of Secchi disk depth (SDD) in Jiaozhou Bay (JZB) are analyzed. Subtle changes in localized small areas are discovered, and main factors affecting the changes are explored. Among natural factors, precipitation and wind play dominant roles in variation in SDD. Human activities have a significant influence on transparency, among which fishery farming has the greatest impact. This is clearly evidenced by the significant improvement of SDD in JZB due to the sharp decrease in human activities caused by coronavirus disease 2019 (COVID-19).Copyright © 2022 The Authors
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Recent years have been associated with the development of various sensor-based technologies in response to the undeniable need for the rapid and precise analysis of an immense variety of pharmaceuticals. In this regard, special attention has been paid to the design and fabrication of sensing platforms based on electrochemical detection methods as they can offer many advantages, such as portability, ease of use, relatively cheap instruments, and fast response times. Carbon paste electrodes (CPEs) are among the most promising conductive electrodes due to their beneficial properties, including ease of electrode modification, facile surface renewability, low background currents, and the ability to modify with different analytes. However, their widespread use is affected by the lack of sufficient selectivity of CPEs. Molecularly imprinted polymers (MIPs) composed of tailor-made cavities for specific target molecules are appealing complementary additives that can overcome this limitation. Accordingly, adding MIP to the carbon paste matrix can contribute to the required selectivity of sensing platforms. This review aims to present a categorized report on the recent research and the outcomes in the combinatory fields of MIPs and CPEs for determining pharmaceuticals in complex and simple matrices. CPEs modified with MIPs of various pharmaceutical compounds, including analgesic drugs, antibiotics, antivirals, cardiovascular drugs, as well as therapeutic agents affecting the central nervous system (CNS), will be addressed in detail.Copyright © 2023 Elsevier B.V.
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We are pleased to provide you with the proceedings of 2022 4th International Conference on Resources and Environment Sciences (ICRES 2022).The conference was expected to be held during June 10-12, 2022 in Bangkok, Thailand, while the situation of COVID-19 pandemic is unpredictable and unstable. Most of conference participants could not travel to attend the conference venue to do oral presentations. Taking all conditions into consideration, conference committee decided to change physical conference into virtual conference. It was held online by ZOOM application successfully during the same date.The conference was highlighted by four outstanding Keynote Speakers and two invited speakers. Keynote speakers include Prof. Kaimin Shih, The University of Hong Kong, China with his topic "Metal Stabilization and Resource Recovery Examples in Urban Environment”;Prof. Nur Islami, University of Riau, Indonesia who presented a talk on "An Valuable Approach to Study Groundwater Contamination in a Shallow Aquifer System”;Prof. Danny Sutanto, University of Wollongong, Australia who shared a speech on "Solid-State Transformer for Smart Power Grid Applications”;Assoc. Prof. Phebe Ding, Universiti Putra Malaysia, Malaysia who presented a talk about "Role of Postharvest Technology in Producing Quality Fresh Horticultural Produces”. Additionally, two excellent invited speakers, Assoc. Prof. Chunrong Jia from University of Memphis, Tennessee, USA with speech title "Apportioning variability of polycyclic aromatic hydrocarbons (PAHs) in the ambient air in the Memphis Tri-State Area, USA”, and Assoc. Prof. Farhad Shahnia from Murdoch University, Australia with speech title "Recent and Future Research on Microgrid Clusters”.Each normal oral presenter had about 12 Minutes of Presentation and 3 Minutes of Question and Answer. Conference was organized in 5 sessions with various topics: Environmental Management, Waste Utilization and Sustainable Development, Wastewater Treatment, Water Analysis and Hydraulic Engineering, Renewable Energy Technology, Chemical Engineering and Fluid Mechanics, Resources and Environmental Science & Sustainable Development, Energy and Chemical Engineering.All accepted papers presented at the ICRES 2022 were included in this volume, which contained three chapters with topics: (1) Environmental Pollution and Control (2) Waste Management and Utilization (3) Clean Energy and Technology. All papers were subjected to peer-review by conference committee members and international reviewers. The papers were selected based on high quality and high relevancy to the conference scope.We would like to express our sincere gratitude to organizing committee and the volunteers who have dedicated their time and efforts in planning, promoting, and helping the conference. We hope that the readers would gain some valuable knowledge from this effort.List of Committees, Statement of Peer Review are available in this Pdf.
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Current approaches and cultures for the economic evaluations of environmental and health policies may suffer from excessive reliance on a standard neoclassic economic toolbox that neglects alternative perspectives. This may prematurely limit the spectrum of available policy options. Here we show how the inclusion of neglected currents of thought such as non-Ricardian economics, bioeconomics and a set of qualitative-quantitative methods from post-normal science leads to richer perspectives for a more inclusive uses of quantitative evidence, and opens the analysis to more possible futures. We also present some case studies in the energy, water, health and climate domains that highlight the point in a practical context for a more policy-oriented audience. We situate our analysis in the context of recent calls in the EU for the inclusion of more perspectives from the social sciences and the humanities in environmental assessment works.Copyright © 2023 The Authors
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The continuous outbreak of COVID-19 results in a large number of therapeutic drugs inevitably entering water bodies through different pathways, and there are problems of accurate and rapid detection in the treatment and ecological evaluation of these drugs. Therefore, it is necessary to establish a method for simultaneous detection of multiple antiviral drugs for treatment of COVID-19 in water. A method for the simultaneous detection of 8 antiviral drugs（ribavirin, oseltamivir, nevirapine, lamivudine,abacavir, stavudine, acyclovir and penciclovir） in source water was developed by optimizing the determining parameters of liquid chromatography-tandem mass spectrometry（LC-MS/MS）. The daughter ion response values of 8 antiviral drugs in this method were relatively high, which was beneficial to the detection of target compounds. The correlation coefficient（r） of the standard curve of 8 antiviral drugs was not less than 0.995 0, the method detection limit（MDL） and the lower limit of determination were in the range of 0.004-0.081 μg/L and 0.013-0.267 μg/L, respectively, and the spike recoveries and RSDs of actual water samples were 81.61%-113.03% and 0.84%-8.12%, respectively.
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There are a range of spatial scales addressed in the papers, from the individual building scale to the cargo ship (Coxon et al., 'Exploring opportunities for sewage testing on cargo ships as a tool to screen seafarers for COVID-19'), subcatchment to sewershed (Nicoll et al., 'Neighbourhood-scale wastewater-based epidemiology for COVID-19'), and city to national (Gilpin et al., A pilot study of wastewater monitoring for SARS-CoV-2 in New Zealand' and Trowsdale et al., 'Establishing New Zealand's national pathogen surveillance system using wastewater-based epidemiology');and all the papers make use of the international literature to provide context for what is a global pandemic. Marrying such information with environmental water samples collected on a daily or weekly basis is problematic. Repurposing data also raises important ethical questions of ownership, confidentiality and responsibility that need to be asked to ensure what we scientists do is both good and right (Price and Trowsdale, 'The ethics of wastewater surveillance for public health').
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Macronutrients (nitrogen—N;phosphorus—P;silicon—Si) play a crucial role in ocean surface waters stimulating the planktonic primary production;in fact, their concentrations are fundamental for the evaluation of the trophic status of the water body and eutrophication phenomena. Loads of nutrients into the sea are mainly represented by river runoff and depuration plant outflows. For this purpose, in the framework of the AdSWiM project, “Managed use of treated urban wastewater for the quality of the Adriatic Sea” levels of N-NO3, N-NO2, N-NH4, Si-Si(OH)4, P-PO4 (dissolved inorganic phosphorus—DIP) and total dissolved phosphorus (TDP) were determined colorimetrically at two sites in the Gulf of Trieste: Lignano Sabbiadoro and San Giorgio di Nogaro. For each site, during the bathing seasons of 2019 and 2020, a sample from the depuration plant (DP) outflow and another one in the bottom seawater near the discharging pipelines were collected. Results showed a strong dilution effect on nutrient levels passing from DPs to the sea, from one to three orders of magnitude and a low and not harmful concentration in seawater. The outflow composition of the two DPs showed that the main fraction of dissolved inorganic nitrogen (DIN) was represented by N-NO3 for Lignano, while in San Giorgio the major contribution came from N-NH4. Concerning phosphorus, Lignano showed a higher content (about 3 times) of P levels than San Giorgio, but a similar percentage composition, DIP:DOP (77:23), compared to the seawater site one DIP:DOP (2:98). Despite the difference between the DPs, no substantial differences were found in the sea sites, demonstrating the negligible effect of the DP outflows in the nutrient levels in the study area.
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Different groups of organic micropollutants including pharmaceuticals and pesticides have emerged in the environment in the last years, resulting in a rise in environmental and human health risks. In order to face up and evaluate these risks, there is an increasing need to assess their occurrence in the environment. Therefore, many studies in the past couple of decades were focused on the improvements in organic micropollutants’ extraction efficiency from the different environmental matrices, as well as their mass spectrometry detection parameters and acquisition modes. This paper presents different sampling methodologies and high-resolution mass spectrometry-based non-target screening workflows for the identification of pharmaceuticals, pesticides, and their transformation products in different kinds of water (domestic wastewater and river water). Identification confidence was increased including retention time prediction in the workflow. The applied methodology, using a passive sampling technique, allowed for the identification of 85 and 47 contaminants in the wastewater effluent and river water, respectively. Finally, contaminants’ prioritization was performed through semi-quantification in grab samples as a fundamental step for monitoring schemes.
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Limited information is available regarding chemical water quality at the tap in Guatemala City, preventing individuals, water utilities, and public health authorities from making data-driven decisions related to water quality. To address this need, 113 participants among households served by a range of water providers across the Guatemala City metropolitan area were recruited as participatory scientists to collect first-draw and flushed tap water samples at their residence. Samples were transported to the U.S. and analyzed for 20 metals and 25 per- and polyfluoroalkyl substances (PFAS). At least one metal exceeded the Guatemalan Maximum Permissible Limit (MPL) for drinking water in 63% of households (n = 71). Arsenic and lead exceeded the MPL in 33.6% (n = 38) and 8.9% (n = 10) of samples, respectively. Arsenic was strongly associated with groundwater while lead occurrence was not associated with location, water source, or provider. One or more PFAS were detected in 19% of samples (n = 21, range 2.1–64.2 ppt). PFAS were significantly associated with the use of plastic water storage tanks but not with location, water source, or provider. Overall, the high prevalence of arsenic above the MPL in Guatemala City tap water represents a potential health risk that current water treatment processes are not optimized to remove. Furthermore, potential contaminants from premise plumbing and storage, including lead and PFAS, represent additional risks requiring further investigation and public engagement.
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Pharmaceuticals and personal care products (PPCPs) were investigated in five wastewater treatment plants (WWTPs), groundwater, irrigated soils, and plants in Amman and Al-Balqa governorates in Jordan. PPCPs were extracted from water samples by solid-phase extraction (SPE) and analyzed by high-performance liquid chromatography coupled with tandem mass spectrometry (HPLC–MS/MS). Carbamazepine, ciprofloxacin, ceftiofur, diclofenac, erythromycin, lincomycin, ofloxacin, pyrimthamine, spiramycin, sulfamethoxazole, sulfapyridine, testosterone, trimethoprim, and thiamphenicol were detected in all raw wastewaters in μg/L, whereas 45 PPCPs were below the detection limits (<0.02 μg/L) in all samples. Na`ur and Abu Nuseir WWTPs showed high PPCPs removal efficiencies in comparison with AL-Baqa`a, Salt, and Fuhais-Mahis WWTPs. Boqorreya spring showed signs of contamination by Salt WWTP effluents as a result of mixing. Irrigation with effluents showed higher carbamazepine concentrations in soils at the top soil layers (0 to 20 cm) in all farms than its concentrations at the root zone (20 to 40 cm) by using drip irrigation system with various plants. In plants, carbamazepine concentration was only detected in high concentration level in mint leaves. In the same farm, diclofenac concentration was detected only in olives and not in twigs and leaves, indicating a high rate of plant uptake especially during the olive’s growth period. Furthermore, plant fruits, leaves, and stems left on the farm after harvesting are generally consumed by cattle, which means entering the food chain of humans.
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The article presents an analysis of the impact of bio-based materials on the environment, with a special focus on polylactic acid (PLA), as it is considered one of the most popular bioplastics in the market. The results show that there are several factors that must be taken into account when choosing the best end-of-life option for this type of material, in agreement with the newly introduced concept of the circular economy, according to the physical–chemical analysis obtained at the end of this study. The ecotoxicity tests showed that all tested materials (PLA spoon, PLA filament, b2w technology bag and cocoa paper tray) could be suitable for incineration with energy recovery without producing dioxines during combustion (chlorine content in all tested materials was below 1.00% w/w). It was also determined that PLA was the material with the highest potential for energy recovery since it presented the highest calorific value and highest carbon content (18.73 MJ/kg and 52.23%, respectively). The biodegradation rate of the different bio-based materials was also tested under different environments during three months, with Baltic Sea water and medium-grain sand being the environments in which the majority of the bio-based materials showed the lowest degradation rates. An additional test in a small-scale electric composter with microbe technology was carried out in order to evaluate the degradation of the studied materials in an environment with controlled conditions, and results showed high values of weight loss for the majority of the bio-based materials (all above 80% weight loss) due to the high temperature that the device could reach during the composting process. Finally, a strategy for providing guidance in selecting routes for the waste management of bioplastics, depending mainly on the available infrastructure and material properties, was proposed as a result of this work. For the case of low- and medium-income countries, an Extended Producer Responsibility (EPR) policy is proposed as a provisional solution to control plastic waste pollution, which should be complemented by regulations and systems aimed at the successful introduction of bioplastics.
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Featured ApplicationThe improvement of effective remote sensing-based approaches to map macrophyte features can provide a baseline of adequate spatiotemporal resolution for 21st century monitoring applications equipped to play a prominent role in the context of medium–large-scale management programs of ecological conservation and scientific research.Macrophytes are of fundamental importance to the functioning of lake ecosystems. They provide structure, habitat, and a food source and are a required component in monitoring programs of lake ecological quality. The key aim of this study is to document the variation in spatial extent and density of macrophytes seasonally between 2015 and 2020 of the Sirmione Peninsula (Lake Garda, Italy), using Sentinel-2 imagery. In addition to this, our results were compared to previous data from imaging spectrometry;individual parameters affecting macrophyte communities were tested, and the possible effect of the COVID-19 lockdown on macrophyte colonization was evaluated. Satellite images allowed the mapping of the spatiotemporal dynamics of submerged rooted macrophytes in order to support monitoring of the shallow water ecosystem under study. Substantial changes were found in both spatial extent and density over the period from 2015 to 2020, particularly in 2019 when there was almost a complete absence of dense macrophytes. Variables found to influence the amount of macrophytes included transparency, chlorophyll–a, water level, winter wave height, and grazing by herbivores. A separate analysis focusing on areas associated with boat transit found a recovery in macrophyte coverage during the period of COVID-19 lockdown. The outcome of the study highlights a decline in the density of the macrophytes and a shift towards deeper areas compared to the situation in 1997. The area examined is part of an internationally important site containing the highest abundance and diversity of overwintering water birds in Italy. Exploiting satellite data at high frequency provided an insight to understand the dynamic changes and interactions with herbivorous birds, environmental factors, and anthropogenic pressures, revealing a delicately balanced and threatened ecosystem.
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The consumption of illicit drugs represents a global social and economic problem. Using suitable analytical methods, monitoring, and detection of different illegal drugs residues and their metabolites in wastewater samples can help combat this problem. Our article defines a method to develop, validate, and practically applicate a rapid and robust analytical process for the evaluation of six naturally occurring cannabinoids (CBG, CBD, CBDV, CBN, THC, THCV), two cannabinoids in acidic form (CBDA, THCA-A), and the major cannabis-related human metabolite (THC-COOH). After SPE offline enrichment, we used a UPLC–ESI-MS/MS system, which permitted the determination of several by-products. Studied matrices were samples of different origins: (i) effluent water from a wastewater treatment plant in the Porto urban area;(ii) environmental water from Febros River, the last left-bank tributary of the Douro River. The multi-residue approach was substantiated and successfully employed to analyze the water samples collected in the above locations. The rapid and precise quantification of nine different cannabinoids in different water samples occurred within nine minutes at the ng L−1 level. The appearance of dozens of ng L−1 of some cannabis secondary metabolites, such as CBD, CBDA, CBN, THCA-A, indicates this plant species’ widespread usage among the general population in the considered area.
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[...]a model of palaeo-flow dynamics, sediment dispersal pattern, depositional setting, cyclicity pattern and basin tectonics is put forward. [...]they suggest that the younger 40Ar/39Ar, Rb–Sr and U–Pb ages in the Kaladgi and Bhima basins could reflect the timing of post-depositional alteration events. [...]of the presence of terrigenous material within the stromatolites, whole-rock geochemical analyses for trace elements and rare earth elements cannot be used for interpretation of seawater chemistry and the redox conditions of the time.
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Effects of drought and aerosol stresses were studied in a factorial experiment based on a Randomized Complete Design with triplicates on two ornamental shrubs. Treatments consisted of four levels of water container (40%, 30%, 20%, and 10% of water volumetric content of the substrate) and, after 30 days from experiment onset, three aerosol treatments (distilled water and 50% and 100% salt sea water concentrations). The trial was contextually replicated on two species: Callistemon citrinus (Curtis) Skeels and Viburnum tinus L. ‘Lucidum’. In both species, increasing drought stress negatively affected dry biomass, leaf area, net photosynthesis, chlorophyll a fluorescence, and relative water content. The added saline aerosol stress induced a further physiological water deficit in plants of both species, with more emphasis on Callistemon. The interaction between the two stress conditions was found to be additive for almost all the physiological parameters, resulting in enhanced damage on plants under stress combination. Total biomass, for effect of combined stresses, ranged from 120.1 to 86.4 g plant−1 in Callistemon and from 122.3 to 94.6 g plant−1 in Viburnum. The net photosynthesis in Callistemon declined by the 70% after 30 days in WC 10% and by the 45% and 53% in WC 20% and WC 10% respectively after 60 days. In Viburnum plants, since the first measurement (7 days), a decrease of net photosynthesis was observed for the more stressed treatments (WC 20% and WC 10%), by 57%. The overall data suggested that Viburnum was more tolerant compared the Callistemon under the experimental conditions studied.
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The COVID-19 pandemic has become a planetary concern that affecting the sustenance of the human population all around the globe. The effective measured has been taken in Malaysia to control the virus transmission by limiting the human vitality which unsurprisingly propitious to the environment. A monitoring study was conducted to assess the water quality status of surface seawater along the Port Dickson coast based on the Malaysian Marine Water Quality Index (MMWQI) and Malaysian Marine Water Quality Standards (MMWQCS) with an interval period of a year (March 2020-March 2021). In situ, water quality parameters incorporate temperature, pH, salinity, conductivity, dissolved oxygen (DO), and total dissolved solids (TDS) were measured at 14 sampling sites to evaluate the biochemical characteristics of water. Surface water samples were collected from the same sites and transported back to Universiti Putra Malaysia for nitrate (NO3-), ammonia (NH3), phosphate (PO4), biochemical oxygen demands (BOD), fecal coliform (Escherichia coli), and total suspended solids (TSS) analyses. The MMWQI showed the status of surface water from the Port Dickson coast was classified as moderate quality (50.41 - 64.05) for both sampling events. However, there are some indexes that showed significant decreases (p< 0.05) in the latter year. The concentration of nutrient pollution such as phosphate, nitrates, ammonia, fecal coliform as well as oil and grease, was decreased by 11.12%, 77.39%, 82.4%, 90.26%, and 99.9% respectively. The water parameters namely TDS, pH, and BOD levels were significantly decreased by 1.77%, 20.73%, and 77.16%. Certain parameters listed in the MMWQS such as temperature, pH, ammonia, fecal coliform, oil and grease were classified as Class 1 in March 2021. These occurrences recorded were greatly influenced by the reduction of the substantial human activities around the recreational beach of Port Dickson followed by the declaration of Movement Control Order (MCO) in Malaysia.